In the present work, synthesis of Y: TiO2 /gC₃N₄ (graphitic carbon nitride) composite have been done by adopting facile hydrothermal method. Green solvent of glycerol has been used for the synthesis of Y: TiO2 /gC₃N₄ which then results the homogeneous nanostructure of the prepared sample. Composites of three different weight ratios of gC₃N₄ (10wt%, 30wt%, 50wt %) were utilized to prepare the samples. The prepared material has been exploited for preparing the photo anode of Dye Sensitized Solar Cells. The synthesized materials have been characterized by XRD and RAMAN for structural analysis. From the analysis of XRD we could observe that the presence of gC₃N₄ in the prepared sample does not modify the phase of TiO₂.Optical properties of the sample have been done by using UV-Vis DRS studies. The morphological studies and compositional analysis were done by FESEM and EDS studies. The J-V characteristic study has been done for the devices with photoanode contains Y: TiO_2, Y: TiO2 /gC₃N₄ (10wt%, 30wt%, 50wt %).