By the process of doping in semiconducting nanomaterials, properties of thematerials such as electronic, optical and photochemical properties can be effectively tuned. Here fluorine doped TiO2 nanostructures were synthesized by microwave assisted solvothermal technique. The X-ray diffraction patterns(XRD) and Raman analysis results of the sample exhibits peaks characteristic of anatase TiO2. From the UV-visible absorption analysis, an increase in visiblelight absorption with no significant change in the absorption edge was noticed. F doped TiO2 nanostructures were found to possess quasi cubic morphology through the transmission electron microscope images and from the presenceof well-defined ring pattern in selected area electron diffraction patterns the polycrystalline nature of the samples were confirmed. The presence of fluorine in the TiO2 lattice was confirmed through the presence of Ti3+ states using Xray photoelectron spectroscopy (XPS) analysis and electron paramagnetic resonance(EPR) analysis respectively. The prepared TiO2, F doped TiO2 nanostructures were coated over fluorine doped tin oxide (FTO) substrates,further they were subjected to dye sensitization and were used as photoanodesin dye sensitized solar cells and their power conversion efficiencies were studied.